Halogenodisilanes: precursors for new disilane derivatives.
نویسندگان
چکیده
Starting from hexachloro- or hexabromodisilane a wide variety of 1,2-disubstituted tetrachlorodisilanes (RSiCl2SiCl2R) [R = Cp (2a), 4-iPrC6H4(SiMe3)N (2b), 2,6-iPr2C6H3(SiMe3)N (2c), (Me3Si)2CH (2d) (Me3Si)3C (2e), (Me3Si)3Si (2f)], tetrabromodisilanes (RSiBr2SiBr2R) [R = Cp (3a), 4-iPrC6H4(SiMe3)N (3b), (Me3Si)3Si (3f)] and the monosubstituted pentahalogenodisilanes CpSiX2SiX3 [X = Cl (4), Br (5)] were prepared. The tetrachlorodisilanes 2a-e are converted to various functionalized disilanes. Ammonolysis of 2a-e leads to the tetraaminodisilanes [RSi(NH2)2Si(NH2)2R] 6a-e. A reduction of 2d with LiAlH4 resulted in the formation of the disilane RSiH2SiH2R [R = (Me3Si)2CH] 7 and the metathesis with Me3SnF yielded the tetrafluorodisilane RSiF2SiF2R [R = (Me3Si)2CH] 8. Treatment of 6d with reagents containing H acidic protons (HX) [X = Br, I and OH] leads under elimination of NH3 to the tetrabromo- R2SiBr2SiBr2R (3d) tetraiodo- RSiI2SiI2R (9) and the tetrahydroxodisilane RSi(OH)2Si(OH)2R (10) [R = (Me3Si)2CH]. Single-crystal X-ray structural analysis of 2d, 6a, 6d, and 9 are reported.
منابع مشابه
A Crystallization-Induced Asymmetric Transformation using Racemic Phenyl Alanine Methyl Ester Derivatives as Versatile Precursors to Prepare Amino Acids
L-Tyrosine and L-Dopa are the precursors in the biological synthesis of amine neurotransmitters. On the other hand, phenylalanine as an aromatic amino acid (AAA) is a precursor in the synthesis of L-Tyrosine and L-Dopa. For some substrates such as amino acids, resolution by the formation of diastereomers offers an attractive alternative. Among different methods in this case, crystallization-ind...
متن کاملAn efficient facile and one-pot synthesis of 2-arylsubstituted benzimidazole derivatives using 1-methyl-3-(2-oxyethyl)-1H-imidazol-3-ium-borate sulfonic acid as a recyclable and highly efficient ionic liquid catalyst at green condition
1-Methyl-3-(2-oxyethyl)-1H-Imidazol-3-ium-Borate Sulfonic Acid ([MOEI]-BSA) was easily prepared and used as a new and highly efficient solid acid catalyst for the synthesis of benzimidazole derivatives with high isolated yields. Various substituted benzimidazoles were synthesized by a combination of o-phenylenediamines and aldehydes in the presence of [MOEI]-BSA with excellent yields in water a...
متن کاملDiamido Complexes of Titanium and Zirconium as Catalyst Precursors for Ethylene Polymerization
A series of 8 new complexes of titanium and zirconium with diamido ligands bearing an ethylene and propylene bridge between the two amido groups were synthesized and tested for ethylene polymerization. Titanium complexes bearing an ethylene bridge between the two amido groups showed higher activities than the derivatives with a propylene bridge. In the case of the zirconium complexes, the p...
متن کاملSynthesis of CuFe2 O4 Nanoparticles by a new co- precipitation method and using them as Efficient Catalyst for One-pot Synthesis of Naphthoxazinones
This paper outlines the synthesis of CuFe2O4 nanoparticles and their catalytic applications. CuFe2O4 nanoparticles were synthesized via microwave-assisted co-precipitation method. The obtained nanoparticles characterized through Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. Vibrating sample magnetometer shows nanoparticles exhibit ferromagnetic be...
متن کاملHigh-pressure structures of disilane and their superconducting properties.
A systematic ab initio search for low-enthalpy phases of disilane (Si2H6) at high pressures was performed based on the minima hopping method. We found a novel metallic phase of disilane with Cmcm symmetry, which is enthalpically more favorable than the recently proposed structures of disilane up to 280 GPa, but revealing compositional instability below 190 GPa. The Cmcm phase has a moderate ele...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Inorganic chemistry
دوره 40 15 شماره
صفحات -
تاریخ انتشار 2001